| 一种简单的溶剂热法合成炭微球 |
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| 引用本文： | 米远祝,刘应亮.一种简单的溶剂热法合成炭微球[J].新型炭材料,2009,24(4). |
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| 作者姓名： | 米远祝 刘应亮 |
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| 作者单位： | 1. 长江大学,化学与环境工程学院,湖北,荆州,434023
2. 暨南大学,化学系,广东,广州,510632 |
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| 基金项目： | 广东省科技基金，广东省千百十人才工程，湖北省科技厅国际合作项目(2006CA014).This work was financially supported by the Science and Technology Project of Guangdong Province，Qian Bai Shi Project of Guangdong Province，International Cooperation Project of Hubei Province |
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| 摘 要： | 利用一种简单的溶剂法合成炭微球.采用无水乙醇作为碳源和溶剂,以无水乙醇还原Ni(Ac)_2得到的Ni作为催化剂,最佳反应条件:温度500℃、时间48h.采用X-射线衍射仪(XRD)、透射电子显微镜(TEM)、扫描电子显微镜(SEM)以及Raman光谱对样品的成分、晶体结构和形貌进行了分析.结果表明:产品为圆球形和纺锤形两种形貌的炭微球,圆球形炭微球直径为1μm～2μm,纺锤形炭微球直径为1μm～2μm,长度为3μm～6μm.此法简便易行,炭微球的产率高达95%以上,且具有较规则的形貌和窄的尺寸分布.
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| 关 键 词： | 溶剂热法 炭微球 合成 |
A simple solvothermal route to synthesize carbon microspheres |
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| MI Yuan-zhu,LIU Ying-liang.A simple solvothermal route to synthesize carbon microspheres[J].New Carbon Materials,2009,24(4). |
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| Authors: | MI Yuan-zhu LIU Ying-liang |
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| Abstract: | Carbon micro-spheres were prepared by a simple solvothermal route in a stainless steel autoclave. Absolute ethanol was used as carbon source and solvent, and nickel as catalyst, obtained by reducing Ni(Ac)_2 in absolute ethanol. Carbon microspheres were obtained at 500 ℃ for 48 h. The samples were characterized by X-ray powder diffractometer, scanning and transmission electron microscopy, and Raman spectroscopy. Results showed that there were acicular and spherical carbon particles in the as-prepared samples. The carbon microspheres had diameters ranging from 1 to 2 μm. and the acicular particles had diameters ranging from 1 to 2 μm and lengths ranging from 3 to 6 μm. The yield of carbon micro-spheres was over 95% with a narrow size distribution and perfect shape. |
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| Keywords: | Solvothemal route Carbon micro-spheres Synthesis |
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