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Effect of quartz particle size on the mechanical behaviour of porcelain tile subjected to different cooling rates
Authors:Agenor De Noni  Dachamir Hotza  Vicente Cantavella Soler  Enrique Sanchez Vilches
Affiliation:1. Instituto Maximiliano Gaidzinski (IMG), 88845-000 Cocal do Sul, SC, Brazil;2. Universidade Federal de Santa Catarina (UFSC), 88040-900 Florianópolis, SC, Brazil;3. Instituto de Tecnologia Cerámica (ITC), 12006 Castellón, Spain;1. National Engineering Laboratory for Hydrometallurgy Cleaner Production Technology, Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Beijing University of Chemical Technology, Beijing 100029, China;1. National Research Council, IDPA, Section of Milan, Via Botticelli 23, I-20133 Milan, Italy;2. Department of Earth Sciences “Ardito Desio”, University of Milan, Via Botticelli 23, 20133 Milan, Italy;3. Ideal Standard International, C.O.E., Ceramic Process Technology, Via Cavassico Inferiore 160, I-32026 Trichiana, BL, Italy;1. Federal Institute of Education, Science and Technology of Santa Catarina (IFSC), Campus Criciúma, 88813-600 Criciúma, SC, Brazil;2. Federal Institute of Education, Science and Technology of Rio Grande do Sul (IFRS), Campus Feliz, 95770-000 Feliz, RS, Brazil;3. Graduate Program in Materials Science and Engineering (PGMAT), Department of Chemical Engineering (EQA), Federal University of Santa Catarina (UFSC), 88040-900 Florianópolis, SC, Brazil;1. Department of Chemical Engineering, Graduate Program on Materials Science and Engineering, Federal University of Santa Catarina, 88040-900 Florianópolis, SC, Brazil;2. Ceramic Materials Group, UNESC, Avenida Universitária 1105, 88806-000 Criciúma, SC, Brazil;1. CNR-ISTEC, Institute of Science and Technology for Ceramics, Via Granarolo 64, Faenza, Italy;2. Centro Ceramico, Via Martelli 26/A, Bologna, Italy
Abstract:Porcelain tile is a high-performance ceramic tile, in which quartz is a major compositional component. After the firing cycle, macroscopic residual stresses develop in the product as a result of rapid cooling. Further, during cooling, the presence of quartz particles also increases natural flaw size. Both phenomena significantly affect the product's mechanical behaviour. This study examines the effect of quartz particle size on the mechanical behaviour of porcelain tile subjected to two very different cooling rates: a rapid or a slow cooling rate. A series of porcelain tile compositions were designed for this purpose, in which quartz particle size was varied. The mechanical behaviour of the sintered pieces was evaluated on the basis of linear elastic fracture mechanics. It was verified that, in the slowly cooled material, the modulus of elasticity and fracture energy increased, and natural flaw size decreased as quartz particle size decreased. However, fracture energy also diminished in pieces that contained excessively small particles, with an advanced state of dissolution. For the rapidly cooled material, though the larger sized quartz particles debonded at higher temperatures owing to thermal stress, their presence, even in small quantities, contributed to natural flaw growth. The lower fracture energy associated with this last type of piece also favours this phenomenon.
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