Microstructure effects on the electrochemical corrosion properties of Mg – 4.1% Ga – 2.2% Hg alloy as the anode for seawater-activated batteries |
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Authors: | Kun Yu Xin Tan Yanan Hu Fuwen Chen Shaojun Li |
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Affiliation: | School of Materials Science and Engineering, Central South University, Changsha 410083, China |
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Abstract: | Mg–Ga–Hg alloy is a new material with special electrochemical corrosion properties that make it ideal for use in seawater-activated battery anodes. The effects of microstructure and phase transformation on the electrochemical properties of the Mg – 4.1% Ga – 2.2% Hg alloy were studied and compared with Mg–Al system alloys. The results show that the Mg – 4.1% Ga – 2.2% Hg alloy, when used as an anode, has an appropriate corrosion potential in a half-cell test and superior electrochemical properties in a single cell assembled with CuCl. The Mg3Hg and Mg21Hg5Ga3 phases of the alloy influence its corrosion behaviour and provide a steady corrosion potential during the discharge process. |
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Keywords: | A. Magnesium B. Galvanostatic C. Anodic dissolution |
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