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The effect of two oleo-gum resin exudate from Ferula assa-foetida and Dorema ammoniacum on mild steel corrosion in acidic media
Authors:M. Behpour  S.M. Ghoreishi  M. Khayatkashani  N. Soltani
Affiliation:aDepartment of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan 87317-51167, Islamic Republic of Iran;bDepartment of Chemistry, Payame Noor University (PNU), Tehran 19395-4697, Islamic Republic of Iran
Abstract:A comparative study of two oleo-gum resins exudate from Ferula assa-foetida (F. assa-foetida) and Dorema ammoniacum (D. ammoniacum), as inhibitors for mild steel corrosion in 2 M HCl solution was investigated by weight loss measurements, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. Potentiodynamic polarization curves indicated that both oleo-gums behave as mixed type inhibitors. The effect of temperature on the inhibition efficiency was studied. At all temperatures, the experimental data fit Langmuir isotherm for both oleo-gum resin exudates. Quantum chemical calculations were performed to illustrate the adsorption process of some specific components of two oleo-gum resin exudates.
Keywords:A. Mild steel   A. Acid solutions   B. Polarization   B. EIS   C. Acid inhibition
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