Corrosion inhibition of copper in neutral chloride media by a novel derivative of 1,2,4-triazole |
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Authors: | Z. Khiati A.A. Othman M. Sanchez-Moreno M.-C. Bernard S. Joiret E.M.M. Sutter V. Vivier |
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Affiliation: | aLISE, UPR 15 du CNRS, Université Pierre et Marie Curie, CP 133, 4 Place Jussieu, 75252 Paris Cedex 05, France;bUniversity Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France;cLaboratoire de Chimie Organique Bioactive, Départment de Chimie, Faculté des Sciences, Université des Sciences et de la Technologie d’Oran, BP 1505 El Mnaouer, Oran, Algeria |
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Abstract: | The efficiency of a new corrosion inhibitor, the bis-(4-amino-5-mercapto-1,2,4-triazol-3-yl)-butane (BAMTB), on copper was investigated in an aerated 3% NaCl solution using various techniques. Voltammetry, chronopotentiometry and electrochemical impedance spectroscopy (EIS) were performed to evaluate the inhibition efficiency of BAMTB. The surface layers were also characterized by Raman micro-spectroscopy and by scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDX). Potentiodynamic polarization curves showed that BAMTB is a mixed-type inhibitor for copper in neutral chloride solution and is even more efficient than the reference compound benzotriazole. |
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Keywords: | A. Copper B. EIS B. Raman spectroscopy B. Polarization C. Neutral inhibition |
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