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纳米级红外光谱用于聚合物的表征
作者姓名:Kevin KJOLLER  Craig PRATER  Roshan SHETTY
作者单位:Vice President of Product Development, Dr. Prater is Chief Technology Offcer, and Mr. Shetty is Chief Executive Offcer, Anasys Instruments, 121 Gray Ave., Ste. 100, Santa Barbara, CA 93101, U.S.A.
摘    要:尽管红外微光谱有广阔的用途,但是由于光学规则与实际设计的局限性,其基本的空间分辨率受到了限制.傅里叶变换红外光谱的空间分辨率局限于3倍的红外辐射波长.通过使用衰减全反射(ATR)的方式,可以将其空间分辨率接近于其辐射波长.纳米级红外光谱(Nano IR)技术可以解决分辨率的限制,提供一种在200 nm及其之上可以测量样品物理和化学性质的方法.

关 键 词:傅里叶变换红外光谱  纳米级  聚合物  空间分辨率  表征  辐射波长  衰减全反射  化学性质

Polymer Characterization Using Nanoscale Infrared Spectroscopy
Kevin KJOLLER,Craig PRATER,Roshan SHETTY.Polymer Characterization Using Nanoscale Infrared Spectroscopy[J].Life Science Instruments,2011,9(1):11-14.
Authors:Kevin KJOLLER  Craig RATER  Roshan SHETTY
Affiliation:Kevin KJOLLER, Craig PRATER, and Roshan SHETTY
Abstract:Despite its widespread applications, infrared microspectroscopy has fundamental spatial resolution limits set by both the laws of optics and practical design constraints. Fourier transform infrared spectroscopy is generally limited to a spatial resolution of three times the wavelength of the IR radiation. With attenuated total reflection (ATR), it may be possible to achieve resolution approaching the wavelength of the radiation. The nanoIR? technique breaks new resolution limits, providing both chemical and physical property data on the scale of ~200 nm and beyond.
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