Synthesis and characterization of coordination polymers of Hg(II) with poly(thiooxamides) |
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Authors: | Milind Khandwe Anjali Bajpai and U D N Bajpai |
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Affiliation: | (1) Department of Post-graduate Studies & Research in Chemistry and Macromolecular Research Centre, R.D. University, 482 001 Jabalpur, India |
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Abstract: | Coordination polymers of Hg(II) with dithiooxamide, poly(ethylene thiooxamide), poly(butane thiooxamide), and poly(hexane thiooxamide) have been synthesized. All coordination polymers are solid compounds insoluble in common organic solvents. Coordination polymers have been characterized by elemental analysis, IR spectra, and thermogravimetric analysis and structures have been proposed leading to coordination of metal through S alone as well as N and S both. Thermal stability of the polymers has also been discussed. |
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Keywords: | Hg(II) coordination polymers poly(thiooxamides) thermally stable polymer polymer-metal complexes |
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