Coordinate chloride and water-assisted assembly of novel 3D-cageworks of cadmium(II) complex with 4-[N,N-bis(2-cyanoethyl)]aminopyridine |
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Authors: | Yi-Zhi Li Jun Ni Zhong Zhang Zhi-Lin Wang |
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Affiliation: | aCoordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China |
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Abstract: | Synthesis and structure of the cadmium(II) complex of CdII(CEAP)2(H2O)(CH3COO)Cl] {CEAP = 4-N,N-bis(2-cyanoethyl)]aminopyridine} has been reported. The structure exhibits a novel 3D-cagework assembly with the assistance of the coordinated chloride anion and water molecule via forming multiple hydrogen bonds with the cyanoethyl arms of CEAP. |
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Keywords: | Cyanoethyl derivative Cadmium complex Weak interaction Self-assembly |
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