| 一乙酰基三苯甲酰基二苄基六氮杂异伍兹烷亚硝化产物的分离和鉴定 |
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| 引用本文： | 庞思平,于永忠,赵信岐. 一乙酰基三苯甲酰基二苄基六氮杂异伍兹烷亚硝化产物的分离和鉴定[J]. 含能材料, 2002, 10(1): 1-3 |
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| 作者姓名： | 庞思平 于永忠 赵信岐 |
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| 作者单位： | 北京理工大学化工与材料学院,北京,100081 |
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| 基金项目： | 国防科工委预研基金资助课题 (12 0 60 45 1867) |
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| 摘 要： | 采用硝酸（65％）／亚硝酸钠体系对一乙酰基三苯甲酰基二苄基六氮杂异伍兹烷进行亚硝解，将两个苄基转换为亚硝基，得到了一乙酰基三苯甲酰基二苄基六氮杂异伍兹烷。采用薄层色谱（TLC）及柱色谱方法，分离出产物中的两种副产物，结构鉴定表明，这两种副产物分别为一乙酰基四苯甲酰基一亚硝基六氮杂异伍兹烷和一乙酰基五苯甲酰基六氮杂异伍兹烷。
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| 关 键 词： | 脱苄 亚硝化 含能材料 鉴定 六硝基六氮杂异伍兹烷 HNIW 一乙酰基三苯甲酰基二苄基六氮杂异伍兹烷 |
| 文章编号： | 1006-9941(2002)01-0001-03 |
| 收稿时间： | 2001-07-16 |
| 修稿时间： | 2001-07-16 |
Separation and Identification of the Nitrosation Products from Monoacetyltribenzoyldibenzylhexaazaisowutzitane |
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| PANG Si-ping,YU Yong-zhong and ZHAO Xin-qi. Separation and Identification of the Nitrosation Products from Monoacetyltribenzoyldibenzylhexaazaisowutzitane[J]. Chinese Journal of Energetic Materials, 2002, 10(1): 1-3 |
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| Authors: | PANG Si-ping YU Yong-zhong ZHAO Xin-qi |
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| Affiliation: | School of Chemical Engineering & Materials Science,Beijing Institute of Technology, Beijing 100081, China;School of Chemical Engineering & Materials Science,Beijing Institute of Technology, Beijing 100081, China;School of Chemical Engineering & Materials Science,Beijing Institute of Technology, Beijing 100081, China |
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| Abstract: | The benzyl groups of monoacetyltribenzoyldibenzylhexaazaisowutzitane were removed successfully by the nitrosification of 65% HNO 3/NaNO 2. And the corresponding nitrosamine product-monoacetyltribenzoyldinitrosohexaazaisowutzitane was obtained. Using thin layer chromatography(TLC) and column chromatography (CC) methods,two kinds of by products of the nitrosation products from monoacetyltribenzoyldibenzylhexaazaisowutzitane were isolated and identified as monoacetyltetrabenzoyl mononitrosohexaazaisowutzitane and monoacetylpentabenzoylhexaazaisowutzitane. |
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| Keywords: | debenzylation nitrosation hexaazaisowutzitane separation |
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