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Corrosion behavior of AZ91 magnesium alloy in dilute NaCl solutions
Authors:Lei Wang  Bo-Ping Zhang  Tadashi Shinohara
Affiliation:aSchool of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;bMaterials Reliability Center, National Institute for Materials Science, Tsukuba Sengen 305-0047, Japan
Abstract:The corrosion behavior of AZ91 magnesium alloy in dilute NaCl solutions was studied using electrochemical measurements, whereby a corrosion map in terms of electrode potential and chloride concentration Cl] was obtained. AZ91 alloy exhibited the corrosion and passivation zones in dilute NaCl solutions. The passivation zone became narrow with increasing Cl]. The values of open-circuit potential were in the passivation zone when the Cl] was less than 0.5 mol/L. XRD patterns showed the presence of the Mg(OH)2, Mg5(CO3)4(OH)2·8H2O and MgO phases in the corrosion product, whereas the latter two phases found in the passive film.
Keywords:AZ91 magnesium alloy  Dilute NaCl solutions  Corrosion map
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