| 聚碳酸亚丙酯改性复合材料的性能 |
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| 引用本文： | 张亚男,汪莉华,卢凌彬,张冲,林强.聚碳酸亚丙酯改性复合材料的性能[J].精细化工,2008,25(2):130-133. |
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| 作者姓名： | 张亚男 汪莉华 卢凌彬 张冲 林强 |
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| 作者单位： | 海南大学,理工学院,热带生物资源教育部重点实验室,海南,海口,570228 |
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| 摘 要： | 通过溶液共混法实现聚碳酸亚丙酯(PPC)与聚乙二醇(PEG)的共混改性,提高PPC的热性能。通过1HNMR、FTIR研究了共混物的相容性,表明聚合物之间没有发生化学反应,两者之间为简单的物理共混,相容性较好,而且共混物的亲水性随着PEG组分的增加而增强。热性能测试结果表明,共混物的玻璃化转变温度(Tg)和热分解温度(Td)都比PPC高,Tg和Td95%最高分别达到51℃和410℃,比PPC提高了29℃和130℃。可用于制备高性能的包装材料。
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| 关 键 词： | 聚碳酸亚丙酯 聚乙二醇 共混 热性能 相容性 |
| 文章编号： | 1003-5214（2008）02-0130-04 |
| 收稿时间： | 2007-08-30 |
| 修稿时间： | 2007-10-11 |
Properties of Modified Polypropylene Carbonate Composite Materials |
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| ZHANG Ya-nan,WANG Li-hua,LU Ling-bin,ZHANG Chong,LIN Qiang.Properties of Modified Polypropylene Carbonate Composite Materials[J].Fine Chemicals,2008,25(2):130-133. |
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| Authors: | ZHANG Ya-nan WANG Li-hua LU Ling-bin ZHANG Chong LIN Qiang |
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| Abstract: | Blending modification of polypropylene carbonate(PPC) and polyethylene glycol(PEG) was finished by solution co-blending,and the thermal performance of PPC was raised.The compatibility of blends was studied by means of 1HNMR and FITR.The results show that no chemical reaction occurs,and the blending effect proves to be good.Glass transition temperatures(Tg) of the blends are 30～51 ℃,the 50% weight loss temperatures of degradation(Td50%) are 205～255 ℃,and the 95% weight loss temperatures of degradation(Td95%) are 390～410 ℃.These temperatures are higher than the Tg(22 ℃),the Td50%(203 ℃) and Td95%(280 ℃) of PPC.The blends can be used in the preparation of high-performance packaging materials. |
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| Keywords: | propylene carbonate polyethylene glycol blend thermal performance compatibility |
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