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改性海泡石对亚甲基蓝的吸附性能
引用本文:王亮,陈孟林,何星存,黄智. 改性海泡石对亚甲基蓝的吸附性能[J]. 过程工程学报, 2009, 9(6): 1095-1098
作者姓名:王亮  陈孟林  何星存  黄智
作者单位:广西师范大学化学化工学院,广西,桂林,541004;广西环境工程与保护评价重点实验室,广西,桂林,541004;广西环境工程与保护评价重点实验室,广西,桂林,541004;广西师范大学环境与资源学院,广西,桂林,541004
基金项目:广西自然科学基金资助项目,广西环境工程与保护评价重点实验室基金资助项目 
摘    要:对海泡石进行了硫酸改性、高温改性、硫酸/高温改性,以亚甲基蓝为吸附对象,研究了改性方法对海泡石吸附性能的影响,对各改性海泡石进行了孔径、孔体积等表征. 结果表明,3种改性方法中,硫酸/高温改性对海泡石吸附性能的提高效果最好,吸附量比改性前提高47.8%,达41 mg/g,吸附等温线符合Langmuir方程. 硫酸/高温复合改性后的海泡石平均孔径达9.74 nm,孔体积达7.064′10-2 cm3/g,分别提高117%和92.6%. 对改性海泡石对亚甲基兰的吸附机理进行了探讨.

关 键 词:海泡石  改性  吸附  亚甲基蓝
收稿时间:2009-05-13
修稿时间:2009-09-04

Adsorption of Methylene Blue onto Activated Sepiolite
WANG Liang,CHEN Meng-lin,HE Xing-cun,HUANG Zhi. Adsorption of Methylene Blue onto Activated Sepiolite[J]. Chinese Journal of Process Engineering, 2009, 9(6): 1095-1098
Authors:WANG Liang  CHEN Meng-lin  HE Xing-cun  HUANG Zhi
Affiliation:School of Environment and Resources, Guangxi Normal UniversitySchool of Environment and Resources, Guangxi Normal UniversitySchool of Environment and Resources, Guangxi Normal UniversitySchool of Environment and Resources, Guangxi Normal University
Abstract:Sepiolite was activated by sulfuric acid, heat and sulfuric acid-heat methods. The adsorption of methylene blue on the modified sepiolite samples was investigated. The pore size and volume of these samples were characterized. The results showed that the sulfuric acid-heat activation method has the best effect in three methods, the adsorptive capacity of modified sepiolite reached 41 mg/g, up by 47.8%. The Langmuir equation could be adaptable to the adsorption isotherm process. The pore size and pore volume of sepiolite activated by acid-heat method reached 9.74 nm and 7.064×10~(-2) cm~3/g, up by 117% and 92.6% respectively. The adsorption mechanism of methylene blue was also studied.
Keywords:sepiolite  activation  adsorption  methylene blue
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