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Solid-state structure of the naphthalene-based n-type semiconductor,and performance improved with Mo-based source/drain electrodes
Authors:Chia-Chun KaoPang Lin
Affiliation:Department of Materials Science and Engineering, National Chiao-Tung University, Hsinchu, Taiwan; Process Technology Division, Display Technology Center, Industrial Technology Research Institute, Hisinchu, Taiwan; Department of Applied Materials and Electro-Optical Engineering, National Chi-Nan University, Nantou, Taiwan
Abstract:The synthesis, single-crystal structures, and device performance of novel naphthalene-diimide are described. The crystal structure has revealed the importance of a withdrawing group on solid-state packing. Metal molybdenum use as source/drain (S/D) electrodes can improve the performance of the bottom-contact device. The bottom-contact device based on a material of N,N′-bis (4-trifluoromethoxybenzyl) naphthalene-1,4,5,8-tetracarboxylic acid diimide has a high mobility of 3.58 × 10−2 cm2 V−1 s−1, a threshold voltage of 1.3 V, and an on/off current ratio of 5.2 × 105.
Keywords:Organic thin-film transistors   n-Type   Naphthalene   Air-stable   Molybdenum
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