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Development of high-capacity nickel-metal hydride batteries using superlattice hydrogen-absorbing alloys
Affiliation:1. Mobile Energy Company, Sanyo Electric Co. Ltd., 7-3-2, Ibukidai-higashimachi Nishi-ku, Kobe, Hyogo 651-2242, Japan;2. Sanyo Energy Twicell Co. Ltd., 307-2 Koyagimachi, Takasaki, Gunma 370-0071, Japan;1. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, PR China;2. College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, PR China;1. Materials Genome Institute & State Key Laboratory of Advanced Special Steels & Shanghai Key Laboratory of Advanced Ferrometallurgy & School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, PR China;2. State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou, 014030, PR China;1. State Key Laboratory of Advanced Special Steels, Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China;2. Materials Genome Institute, Shanghai University, Shanghai, 200444, China;3. Shanghai Institute of Materials Genome, Shanghai University, Shanghai, 200444, China;4. CompuTherm LLC, Middleton, WI, 53562, USA;1. State Key Laboratory for Advanced Metals and Materials, Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China;2. Department of Applied Physics, EETAC, Polytechnic University of Catalonia, Castelldefels 08860, Spain;3. State Grid Smart Research Institute, Beijing 102211, China;1. BASF-Ovonic, 2983 Waterview Drive, Rochester Hills, MI 48309, USA;2. FDK Twicell Co., Ltd., 307-2 Koyagimachi, Takasaki 370-0071, Gunma, Japan;3. Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA;1. School of Materials Science and Engineering, Key Laboratory of Advanced Energy Storage Materials of Guangdong Province, South China University of Technology, Guangzhou, 510641, People''s Republic of China;2. Sihui City Double Win Industry CO., LTD., People''s Republic of China;3. Department of Rare-Earth Metal, Guangdong General Research Institute of Industrial Technology, 510650, People''s Republic of China
Abstract:New R–Mg–Ni (R: rare earths) superlattice alloys with higher-capacity and higher-durability than the conventional Mm–Ni alloys with CaCu5 structure have been developed. The oxidation resistibility of the superlattice alloys has been improved by optimizing the alloy composition by such as substituting aluminum for nickel and optimizing the magnesium content in order to prolong the battery life. High-capacity nickel-metal hydride batteries for the retail market, the Ni-MH2500/900 series (AA size type 2500 mAh, AAA size type 900 mAh), have been developed and commercialized by using an improved superlattice alloy for negative electrode material.
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