Advanced air-breathing direct methanol fuel cells for portable applications |
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Affiliation: | 1. Shandong Vocational College of Light Industry, Zibo 255300, PR China;2. Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Institute of Theoretical Chemistry, Shandong University, Jinan 250100, PR China;3. School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, PR China;1. Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia;2. Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia;1. Faculty of Science and Technology, Tokyo University of Science 2641 Yamazaki, Noda-shi, Chiba-ken, 278-8510, Japan;2. Research Center for Green and Safety Sciences, Tokyo University of Science 1-3 Kagurazaka, Shinjuku, Tokyo, 162-8601, Japan;1. Research Center for Nano-Materials and Energy Technology (RCNMET), School of Science and Technology, Sunway University, Bandar Sunway, Petaling Jaya, 47500, Selangor Darul Ehsan, Malaysia;2. Department of Engineering, Lancaster University, Lancaster, LA1 4YW, UK;3. Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600, UKM Bangi, Selangor, Malaysia;4. Department of Mechanical Engineering, Faculty of Engineering, University of Malaya, 50603, Kuala Lumpur, Malaysia;1. Instituto de Ingeniería Electroquímica y Corrosion and CONICET, Universidad Nacional del Sur (UNS), Av. Alem 1253 Bahía Blanca B8000CPB, Argentina;2. Instituto de Física del Sur (IFISUR), Departamento de Física, Universidad Nacional del Sur (UNS), CONICET, Av. Alem 1253 Bahía Blanca B8000CPB, Argentina;3. Instituto de Ingeniería Electroquímica y Corrosion and CIC, Universidad Nacional del Sur (UNS), Av. Alem 1253 Bahía Blanca B8000CPB, Argentina;1. Department of Mechanical Engineering, Graduate School of Engineering, Osaka University, Suita-shi, Osaka 565-0871, Japan;2. Department of Mechanical Engineering, Faculty of Science and Technology, Tokyo University of Science, Noda-shi, Chiba 278-8510, Japan;3. Department of Mechanical Engineering, School of Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552, Japan |
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Abstract: | A novel MEA is fabricated to improve the performance of air-breathing direct methanol fuel cells. A diffusion barrier on the anode side is designed to control methanol transport to the anode catalyst layer and thus suppressing the methanol crossover. A catalyst coated membrane with a hydrophobic gas diffusion layer on the cathode side is employed to improve the oxygen mass transport. It is observed that the maximum power density of the advanced DMFC with 2 M methanol solution achieves 65 mW cm−2 at 60 °C. The value is nearly two times more than that of a commercial MEA. At 40 °C, the power densities operating with 1 and 2 M methanol solutions are over 20 mW cm−2 with a cell potential at 0.3 V. |
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