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生物质基碳水化合物催化转化制备乳酸的研究进展
引用本文:石 宁,唐石云,罗文艳,杨嘉鹏,马 博,骆钱江.生物质基碳水化合物催化转化制备乳酸的研究进展[J].新能源进展,2018,6(2):102-112.
作者姓名:石 宁  唐石云  罗文艳  杨嘉鹏  马 博  骆钱江
作者单位:1. 贵州理工学院,化学工程学院,贵阳 550003; 2. 广东省新能源和可再生能源研究开发与应用重点实验室,广州 510640
基金项目:广东省新能源和可再生能源研究开发与应用重点实验室开放基金项目(Y607sc1001)
摘    要:生物质基碳水化合物(纤维素、淀粉、葡萄糖、果糖等)是自然界最丰富的可再生资源,将其用于生产人类生存所必需的有机化学品是当前的一个重要研究方向。其中,将生物质催化转化为乳酸及其衍生化学品是生物质高值利用的途径之一,并在近年的研究中取得了显著进展。本文对生物质基糖类催化转化制备乳酸进行了详细的总结和评述,着重分析了葡萄糖转化为乳酸的转化过程及催化剂研究,讨论了葡萄糖异构化及果糖逆醛醇反应的催化剂机理,并对今后该领域的研究前景进行了展望。

关 键 词:生物质  碳水化合物  乳酸  催化转化  异构化  
收稿时间:2018-01-08

Advances in Catalytic Conversion of Biomass Derived Carbohydrates into Lactic Acid
SHI Ning,TANG Shi-yun,LUO Wen-yan,YANG Jia-peng,MA Bo,LUO Qian-jiang.Advances in Catalytic Conversion of Biomass Derived Carbohydrates into Lactic Acid[J].Advances in New and Renewable Energy,2018,6(2):102-112.
Authors:SHI Ning  TANG Shi-yun  LUO Wen-yan  YANG Jia-peng  MA Bo  LUO Qian-jiang
Affiliation:1. School of Chemical Engineering, Guizhou Institute of Technology, Guiyang 550003, China;
2. Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
Abstract:Biomass derived carbohydrates (cellulose, starch, glucose, fructose) is the most abundant renewable resource, which is also viewed as carbon source for producing liquid fuel and platform chemicals in the future. Selectively convert the biomass resources into lactic acid and lactate with some catalysts under hydrothermal condition is one route for higher value application of biomass resources. This paper reviewed some recent research advances in the catalytic synthesis of lactic acid from carbohydrates, with an emphasis on the chemical reaction process and the catalysts. The isomerization mechanics of glucose and retro-aldol condensation mechanism of fructose were discussed. The future research tendency in this field was concluded.
Keywords:biomass  carbohydrates  lactic acid  catalytic conversion  isomerization  
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