SORPTION BEHAVIOR AND PRELIMINARY PERVAPORATION RESULTS OF CROSS-LINKED POLYVINYLALCOHOL AND POLYDIMETHYLSILOXANE MEMBRANES PREPARED FOR THE SEPARATION OF WATER-ETHYLACETATE MIXTURES |
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Authors: | Y Salt A Hasano lu S Din er |
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Affiliation: |
a Yildiz Technical University, Chemical Engineering Department, Istanbul, Turkey. |
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Abstract: | Since pervaporation process is the coupling of solution and diffusion mechanisms, a sorption study was carried out with membranes prepared by cross-linking polyvinylalcohol (PVA) and polidimethylsiloxane (PDMS). Tartaric acid (Tac) was used as the cross-linking agent for PVA, and a commercial cross-linking agent was used for PDMS. Sorption experiments were carried out at 30-50°C temperature range in pure water and ethyl acetate using the films prepared. The PVA and PDMS films prepared preferentially sorb water and ethylacetate, respectively. A pervaporation study at 30°C was carried out for pure ethylacetate and pure water, and mixtures of ethylacetate containing 2 and 2.5 wt% water using 100 μm thick PVA membrane. The results indicate that the PVA membrane prepared is extremely selective for water. |
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Keywords: | Pervaporation Sorption Tartaric Acid Polyvinylalcohol Polydimethylsiloxane |
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