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铝灰用于钢包渣改质剂试验
引用本文:李燕龙,张立峰,杨文,王琳舒.铝灰用于钢包渣改质剂试验[J].钢铁,2014,49(3):17-23.
作者姓名:李燕龙  张立峰  杨文  王琳舒
作者单位:北京科技大学冶金与生态工程学院, 北京 100083
基金项目:国家自然科学基金资助项目(51274034,51334022)
摘    要: 低铝铝灰中单质Al质量分数小于5%,循环再利用性较差。对其用于钢包渣改质剂的可行性做了试验,发现铝灰中除单质Al外,AlN也是一种还原剂。试验采用渣钢比1 ∶10放入MgO坩埚中加热到1600℃,将铝灰和石灰与萤石按4∶6∶1混合后加入坩埚中,保温90min后自然冷却。试验结果表明低铝铝灰具有很好的还原性,可将钢包渣中w((FetO))由31.17%降低至3.24%,钢中w([O])由480×10-6降低至17×10-6,钢中w([S])由190×10-6降低至75×10-6,但该过程会造成钢液增[N],w([N])由66×10-6增至129×10-6。

关 键 词:铝灰  钢包渣  改质剂  氮化铝  
收稿时间:2013-04-09

Development of Ladle Slag Reducer Using Aluminum Dross
LI Yan-long,ZHANG Li-feng,YANG Wen,WANG Lin-shu.Development of Ladle Slag Reducer Using Aluminum Dross[J].Iron & Steel,2014,49(3):17-23.
Authors:LI Yan-long  ZHANG Li-feng  YANG Wen  WANG Lin-shu
Affiliation:School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Abstract:In the current study,ladle slag reducer was made using aluminum dross that contained a low content of metallic aluminum and high percentage of AlN.Laboratory experiments were performed in MgO crucibles under 1600℃ with a 1∶10 dross-steel ratio and a 4∶6∶1 dross-lime-fluorite, the samples were cooled by nature convection after 90 min heat preservation.The results indicate that both AlN and metallic aluminum in the dross could work as reducer to remove the oxygen in BOF slags carried on.Using this kind of aluminum dross,the w((FetO)) in BOF slag could be decreased from 31.2% to 3.2%,w([O]) in the steel can be lowered from 480×10-6 and 17×10-6,and w([S]) in the steel is lowered 190×10-6 and 75×10-6.However,the w([N]) in the steel is increased from 66×10-6 to 129×10-6.
Keywords:Aluminum dross  Ladel slag  Reducer  AlN  
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