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Synthesis of acetonitrile and related compounds from CO-H2-NH3 over Mo/SiO2
Authors:Takashi Tatsumi  Shigeki Kunitomi  Jun Yoshiwara  Atsushi Muramatsu  Hiro-o Tominaga
Affiliation:(1) Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo, Hongo, 113 Tokyo, Japan
Abstract:In the reaction of CO-H2-NH3 on Mo/SiO2 catalysts, HCN is formed and is considered to be the principal intermediate for the formation of CH3CN. At low temperature methylamine is also formed.
Keywords:Ammonia  carbon monoxide  hydrogen  molybdenum  acetonitrile'
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