Isotactic copolymerization of methyl methacrylate (MMA) with alkyl acrylates |
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| Authors: | Hai Deng Kazuo Soga Takeshi Shiono |
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| Affiliation: | (1) School of Materials Science, Japan Advanced Institute of Science and Technology, 15 Asahidai, 923-12 Tatsunokuchi, Ishikawa, Japan;(2) Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatula, Midori-ku, 227 Yokohama, Japan |
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| Abstract: | Summary Copolymerization of methyl methacrylate(MMA) and alkyl acrylates [t-butyl(tBA) and 2-ethylhexyl(OA)] was realized from a short living pre-PMMA. The poly(MMA-co-tBA) and poly(MMA-co-OA) obtained with rac-Me2Si(Ind)2ZrMe2 were characterized as random isotactic copolymers. Whereas, corresponding syndio-rich atactic random copolymers were obtained with Cp2ZrMe2. |
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