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Photocatalytic Decomposition of Formic Acid Under Visible Light Irradiation Over V-ion-implanted TiO2 Thin Film Photocatalysts Prepared on Quartz Substrate by Ionized Cluster Beam (ICB) Deposition Method
Authors:Jinkai Zhou  Masato Takeuchi  X. S. Zhao  Ajay K. Ray  Masakazu Anpo
Affiliation:(1) Department of Chemical and Biomolecular Engineering, Faculty of Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore, 119260, Singapore;(2) Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka 599-8531, Japan
Abstract:Unique visible-light-responsive TiO2 photocatalysts (λ>450 nm) were successfully developed by implantation of V ions into the TiO2 thin films prepared on a quartz substrate by an ionized cluster beam (ICB) deposition method. After V ions implantation into TiO2 thin film, the photocatalytic activity of the thin films for the decomposition of formic acid into CO2 and H2O was found to proceed efficiently under visible light irradiation longer than 450 nm. The TiO2 thin film photocatalysts were characterized by XRD, UV-vis, XPS, FE-SEM and AFM.
Keywords:TiO2 thin films  ionized cluster beam deposition method  V ions implantation  visible-light-responsive TiO2 photocatalysts  decomposition of formic acid
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