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A Kinetic Study of the Liquid Phase Acetoxylation of α-Pinene
Authors:M Golets  S Ajaikumar  W Larsson  D Blomberg  H Grundberg  J W?rn?  T Salmi  J-P Mikkola
Affiliation:1. Technical Chemistry, Department of Chemistry, Chemical-Biological Center, Ume? University, 90187, Ume?, Sweden
2. Processum Biorefinery Initiative AB, 89186, ?rnsk?ldsvik, Sweden
3. Aditya Birla Domsj? Fabriker AB, 89186, ?rnsk?ldsvik, Sweden
4. Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, ?bo Akademi University, Biskopsgatan 8, 20500, Turku, Finland
Abstract:The present study introduces kinetic modeling of liquid phase ??-pinene acetoxylation with acetic acid over an ion-exchange resin catalyst. The reaction was carried out in a laboratory scale high-pressure autoclave. ??-terpinyl (35?wt%) and bornyl (40?wt%) acetates were the primary products. The predominant reaction pathways were identified and evaluated.
Keywords:
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