| 3-硝基-4-甲氧基乙酰苯胺的选择性催化加氢 |
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| 引用本文： | 马荣华,胡爽,辛俊娜,侯洁,郭方,吕荣文,吕连海.3-硝基-4-甲氧基乙酰苯胺的选择性催化加氢[J].精细化工,2006,23(11):1138-1141. |
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| 作者姓名： | 马荣华 胡爽 辛俊娜 侯洁 郭方 吕荣文 吕连海 |
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| 作者单位： | 大连理工大学,精细化工国家重点实验室,辽宁,大连,116012 |
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| 摘 要： | 以改性骨架镍为催化剂,催化3-硝基-4-甲氧基乙酰苯胺(NMA)液相选择加氢制备了3-氨基-4-甲氧基乙酰苯胺(AMA)。在反应温度60℃,压力0.15 MPa,m(催化剂)/m(NMA)=1/10时,反应1 h,NMA转化率为100%,AMA的选择性达99.9%。分别以乙醇和甲醇为溶剂考察了催化剂的寿命,在乙醇中催化剂连续套用42次,转化率均为100%,AMA选择性只由99.2%下降到97.0%;在甲醇中连续套用15次,转化率均为100%,AMA选择性均高于99.5%。
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| 关 键 词： | 改性骨架镍 3-硝基-4-甲氧基乙酰苯胺 催化加氢 3-氨基-4-甲氧基乙酰苯胺 |
| 文章编号： | 1003-5214（2006）11-1138-04 |
| 收稿时间： | 2006-04-27 |
| 修稿时间： | 2006-04-272006-07-11 |
Selective Catalytic Hydrogenation of 3-Nitro-4-methoxyacetanilide |
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| MA Rong-hua,HU Shuang,XIN Jun-na,HOU Jie,GUO Fang,L Rong-wen,L Lian-hai.Selective Catalytic Hydrogenation of 3-Nitro-4-methoxyacetanilide[J].Fine Chemicals,2006,23(11):1138-1141. |
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| Authors: | MA Rong-hua HU Shuang XIN Jun-na HOU Jie GUO Fang L Rong-wen L Lian-hai |
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| Affiliation: | State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, Liaoning, China |
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| Abstract: | Modified skeletal Ni catalyst was used in liquid phase selective hydrogenation of 3-nitro-4-methoxyacetanilide(NMA) to prepare 3-amino-4-methoxyacetanilide(AMA).The conversion was 100% and the selectivity was up to 99.9% under the conditions of 60 ℃,0.15 MPa,1 h and m(catalyst)∶m(NMA)=1∶10.The catalyst showed excellent performance in either ethanol or methanol.When the catalyst was repeatedly used for 42 times in ethanol,the conversion of NMA retained 100% and the selectivity of AMA decreased only to 97.0% from 99.2%.When the catalyst was used for 15 times in methanol,the conversion retained 100% and the selectivity of AMA was always higher than 99.5%. |
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| Keywords: | modified skeletal-Ni 3-nitro-4-methoxyacetanilide catalytic hydrogenation 3-amino-4-methoxyacetanilide |
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