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金属间化物Nd(Fe_(1-x)Co_x)_(10)V_2的磁性能机制
引用本文:罗广圣,曾贻伟. 金属间化物Nd(Fe_(1-x)Co_x)_(10)V_2的磁性能机制[J]. 金属学报, 2002, 0(3)
作者姓名:罗广圣  曾贻伟
作者单位:南昌大学化学与材料科学学院 南昌330047(罗广圣),北京师范大学物理系 北京100875(曾贻伟)
基金项目:江西省自然科学基金资助项目1500147
摘    要:通过X射线衍射.磁测量和M(?)ssbauer谱测定了Nd(Fe1-Cox)10V2的结构和磁性.结果表明,Nd(Fe1-xCox)10V2(x=0,0.05,0.10,0.15,0.20)化合物的晶体结构均为ThMn12型结构;随着 Co含量x的增大,晶格常数将单调减少.Co原子的替代将导致化合物各个Fe晶位上的磁超精细场值Bhf逐渐增加.Co部分取代Nd(Fe1-xCox)10V2中的Fe原子时.将择优占据8i铁晶位.取向样品NdFe10V2的热磁曲线和变温M(?)ssbauer谱研究结果表明.该化合物在T=120K条件下存在自旋重取向现象.

关 键 词:Nd(Fe1-xCox)10V2  择优占位  自旋重取向  饱和磁矩  M(?)ssbauer谱

MAGNETIC PROPERTY MECHANISM OF THE INTER-METALLIC COMPOUNDS Nd(Fe_(1-x)Co_x)_(10)V_2
LUO GuangshengCollege of Chemistry and Material Sciences,Nanchang University,Nanchang ZENG Yiwei. MAGNETIC PROPERTY MECHANISM OF THE INTER-METALLIC COMPOUNDS Nd(Fe_(1-x)Co_x)_(10)V_2[J]. Acta Metallurgica Sinica, 2002, 0(3)
Authors:LUO GuangshengCollege of Chemistry  Material Sciences  Nanchang University  Nanchang ZENG Yiwei
Affiliation:LUO GuangshengCollege of Chemistry and Material Sciences,Nanchang University,Nanchang 330047ZENG YiweiDepartment of Physics,Beijing Normal University,Beijing 100875Correspondent: LUO Guangsheng,associate professor,Tel:
Abstract:The crystal structure and magnetic properties of Nd(Fe1-xCox)10V2 have been mea-sured by X-ray diffraction, magnetic properties measurements and Mossbauer spectroscopy methods. The following conclusions are obtained: all Nd(Fe1-xCox)10V2(x=0, 0.05, 0.10, 0.15, 0.20) compounds crystallize in ThMn12-type structure, the lattice constants decrease monotonically with increasing of Co atom concentration. Substitution of Co for Fe leads to a monotonic increase of the hyperfine in-teraction field Bhf on all Fe sites. Furthermore,the experiment results show that Co atom occupies preferentially 8i Fe site in Nd(Fe1-xCox)10V2 compounds.The experimental results of theromagnetic curves and Mossbauer spectroscopy at different temperatures indicate that there exists a spin reorien-tation at T=120 K in the oriented sample NdFe10V2.
Keywords:Nd(Fe1_xCox)1oV2   preferential occupation   spin reorientation   saturation atom moment   Mossbauer spectroscopy
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