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网眼多孔陶瓷浸渍成型工艺的研究
引用本文:朱新文,江东亮,谭寿洪. 网眼多孔陶瓷浸渍成型工艺的研究[J]. 无机材料学报, 2001, 16(6): 1144-1150
作者姓名:朱新文  江东亮  谭寿洪
作者单位:中国科学院上海硅酸盐研究所高性能陶瓷和超微结构国家重点实验室 上海 200050
摘    要:
采用一种具有三维网状结构和连通气孔的氨酯海绵作为骨架来制备网眼多孔陶瓷.采用一种亲水憎水平衡值(HLB)>12的表面活性剂溶液对海绵体孔筋表面进行改性处理,改善了海绵与水基浆料之间的粘附性,增加了浆料涂覆量.研究了浆料固含量、有机泡沫体网眼大小、对辊间距和挤压次数对浆量涂覆量及结构均匀性的影响.结果表明:浆料固含量和对辊间距是影响涂覆量及结构均匀性的最主要因素.还发现网眼烧结体的相对密度与相对对辊间距具有很好的线性关系,这为预测和优化材料的渗透率及机械强度提供了一定的依据.

关 键 词:多孔陶瓷  浸渍工艺  碳化硅  浆料  
文章编号:1000-324(2001)06-1144-07
收稿时间:2000-10-12
修稿时间:2000-10-12

Impregnating Process of Reticulated Porous Ceramics Using Polymeric Sponges as the Templates
ZHU Xin-Wen,JIANG Dong-Liang,TAN Shou-Hong. Impregnating Process of Reticulated Porous Ceramics Using Polymeric Sponges as the Templates[J]. Journal of Inorganic Materials, 2001, 16(6): 1144-1150
Authors:ZHU Xin-Wen  JIANG Dong-Liang  TAN Shou-Hong
Affiliation:State Key Laboratory of High Performance Ceramics and Superfine Microstructure; Shanghai Institute of Ceramics; Chinese Academy of Sciences; Shanghai 200050; China
Abstract:
Commercial polyurethane sponges with three dimensional network and open cells, were used as the templates to produce SiC based reticulated porous ceramics (RPCs) from ceramic slurries by the replication process. Surface modification of polyurethane sponges was carried out by a surfactant with hydrophile-lipophile balance (HLB) value>l2. This pretreatment is beneficial to increase the adhesion of the slurry to the sponge. Effects of slurry solids content, pore diameter of sponge, distance between the rolls and the number of passes on the loading of slurry on the sponges and macrostructure of RPCs, were investigated in detail. The results indicate that the macrostructure of RPCs depends strongly on the slurry solids content and relative distance. The relative density of RPCs has a good linear relationship with the relative distance, which is very important to predict and optimize the permeability and mechanical properties of RPCs.
Keywords:reticulated porous ceramics  impregnating process  silicon carbide  slurry
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