Cross sections for the photoionization of H2(X1Σg+, vi = 0–14) with the formation of H2+(X2Σg+, vf = 0–18), and vibrational overlaps and Rn-centroids for the associated vibrational transitions期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Cross sections for the photoionization of H2(X1Σg+, vi = 0–14) with the formation of H2+(X2Σg+, vf = 0–18), and vibrational overlaps and Rn-centroids for the associated vibrational transitions

Authors:	M.R. Flannery H. Tai D.L. Albritton

Affiliation:	1. Joint Institute for Laboratory Astrophysics, University of Colorado Boulder, Colorado 80309 USA;2. National Bureau of Standards, Boulder, Colorado 80309 USA

Abstract:	Cross sections for the photoionization of $H_{2} (X^{1} Σ_{g}^{+})$ , initially in vibrational levels v_i = 0–14, with the production of $H_{2}^{+} (X^{2} Σ_{g}^{+})$ in vibrational levels v_f = 0–18 are tabulated for the full vibrational array at 24 photon wavelengths ranging from 912 Å to 450 Å. The associated vibrational overlap integrals 〈v_ifv_f〉 and R-centroids, $〈v_{i} \|R^{n} \|v_{f} 〉〈v_{i} \|v_{f} 〉, n = 1 and 2$ are also presented together with accurate curve fits of the bound-free ( $H_{2} -H_{2}^{+} + e$ ) electronic matrix elements.

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