| PVA平均聚合度的优化控制方法及其生产应用 |
| |
| 引用本文： | 刘世均.PVA平均聚合度的优化控制方法及其生产应用[J].石油与天然气化工,2011,40(6):562-566,537. |
| |
| 作者姓名： | 刘世均 |
| |
| 作者单位： | 四川大学化学工程学院;中国石化四川维尼纶厂; |
| |
| 摘 要： | 深入分析了影响PVA平均聚合度的因素。提出了控制PVA平均聚合度的工艺优化措施。根据自由基聚合反应的特点，结合大量生产数据，推导出了平均聚合度与甲醇配比、聚合率的量化关系式。在甲醇配比引入上述关系式的基础上，进一步建立了聚合率、甲醇配比、引发剂添加率、反应时间四者的量化关系式，使之适用范围更宽。通过将优化控制方法应用于多品种的开发和生产中，发现对PVA产品平均聚合度的稳定控制起到了良好效果。
|
| 关 键 词： | 聚乙烯醇 平均聚合度 聚合率 优化控制 |
Optimal Control Measures for Average Polymerization Degree of PVA and Its Production Applications |
| |
| Liu Shijun.Optimal Control Measures for Average Polymerization Degree of PVA and Its Production Applications[J].Chemical Engineering of Oil and Gas,2011,40(6):562-566,537. |
| |
| Authors: | Liu Shijun |
| |
| Affiliation: | Liu Shijun1,2(1.School of Chemical Engineering,Sichuan University,Chengdu 610065,Sichuan,China;2.SINOPEC Sichuan Vinylon Factroy,Chongqing 401254,China).CHEMICAL ENGINEERING OF OIL & GAS,VOL.40,NO.6,pp562～566,2011(ISSN 1007-3426,IN CHINESE) |
| |
| Abstract: | In this paper,the optimal control measures for average polymerization degrees of polyvinyl alcohol(PVA) were proposed by thoroughly analyzing the main influence factors.Based on the reaction mechanism of free radical polymerization and the large amount of production data,the quantification relationship of average polymerization degree of PVA with methanol ratio and conversion of polymerization was derived.With introduction of methanol ratio into the above equation,the quantification relationship among the p... |
| |
| Keywords: | polyvinyl alcohol(PVA) average polymerization degree conversion of polymerization optimal control |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《石油与天然气化工》浏览原始摘要信息 |
|
点击此处可从《石油与天然气化工》下载全文 |
|
