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聚丙烯用附着力促进剂研究进展
引用本文:乔泽敏,黄志峰,李瑜,汤汉良,罗辉. 聚丙烯用附着力促进剂研究进展[J]. 化工进展, 2012, 31(9): 2006-2010
作者姓名:乔泽敏  黄志峰  李瑜  汤汉良  罗辉
作者单位:1.西安交通大学能源与动力工程学院,陕西 西安 710049;2西安交通大学理学院,陕西 西安 710049;3广州浩宇化工科技有限公司,广东 广州 510540
摘    要:从氯化聚丙烯(CPP)的改性、附着力促进剂的无氯化和水性化三个方面综述了聚丙烯(PP)用附着力促进剂的研究进展。介绍了不饱和酸(酐)改性CPP的研究和无氯附着力促进剂的制备方法,阐述了机械法、相反转法、自乳化法和乳液聚合法制备水性附着力促进剂时各自的优缺点和适用范围,总结了可控自由基聚合在PP用附着力促进剂领域的应用。最后指出在进一步的研究中还需要提高无氯附着力促进剂与面漆树脂相容性和水性附着力促进剂的稳定性。

关 键 词:附着力促进剂  氯化聚丙烯  改性  无氯  水性

Research progress of polypropylene adhesion promoter
QIAO Zemin,HUANG Zhifeng,LI Yu,TANG Hanliang,LUO Hui. Research progress of polypropylene adhesion promoter[J]. Chemical Industry and Engineering Progress, 2012, 31(9): 2006-2010
Authors:QIAO Zemin  HUANG Zhifeng  LI Yu  TANG Hanliang  LUO Hui
Affiliation:1 School of Energy and Power Engineering,Xi’an Jiaotong University,Xi’an 710049,Shaanxi,China; 2School of Science,Xi’an Jiaotong University,Xi’an 710049,Shaanxi,China 3 Guangzhou Haoyu Chemical Industry Co.,Ltd.,Guangzhou 510540,Guangdong,China
Abstract:The recent development of polypropylene adhesion promoter is reviewed,including modification of chlorinated polypropylene,chlorine-free adhesion promoter and waterborne adhesion promoter.The modification of chlorinated polypropylene with unsaturated anhydride and the preparation of chlorine-free adhesion promoter are introduced.Mechanical method,phase inversion technique,spontaneous emulsification method and emulsion polymerization technique are used to prepare waterborne adhesion promoter,and the characteristics of each methods are presented.The application of controlled radical polymerization is also summarized.The compatibility between topcoat and chlorine-free adhesion promoter and the stability of waterborne adhesion promoter should be improved in further study.
Keywords:adhesion promoter  chlorinated polypropylene  modification  chlorine-free  waterborne
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