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合成气直接制低碳烯烃技术进展与经济性分析
引用本文:杨学萍,董丽. 合成气直接制低碳烯烃技术进展与经济性分析[J]. 化工进展, 2012, 31(8): 1726-1731
作者姓名:杨学萍  董丽
作者单位:中国石化上海石油化工研究院,上海 201208
摘    要:合成气直接制低碳烯烃是近年来研究较多的石油替代路线合成重要有机化学品的工艺之一。本文对该工艺的技术进展,包括催化剂和工艺的开发情况进行了综述,认为高催化活性、高选择性催化剂是打破产品分布受ASF规律限制的关键,而反应器和新工艺的开发也可提高低碳烯烃的收率,减少CO2排放,并通过与其它成熟技术的组合,推进该工艺的工业化进程。由初步的技术经济性分析可见,与传统蒸汽裂解和经甲醇制烯烃工艺相比,合成气直接制低碳烯烃工艺具有较强的经济竞争力。

关 键 词:合成气  费托  低碳烯烃  技术进展  经济性

Technical progress and economical ananysis on the direct production of light olefins from syngas
YANG Xueping,DONG Li. Technical progress and economical ananysis on the direct production of light olefins from syngas[J]. Chemical Industry and Engineering Progress, 2012, 31(8): 1726-1731
Authors:YANG Xueping  DONG Li
Affiliation:Shanghai Research Institute of Petrochemical Technology,SINOPEC,Shanghai 201208,China
Abstract:The production of light olefins from syngas is one of the hot topics to prepare important organic chemicals from non-oil resources.Technical progress in the process,including research on catalysts,reactors and process,was summarized.It is believed that highly active and selective catalysts are key to break the limit of ASF product distribution.Meanwhile,new reactors and novel processes development also contribute to the high yield of light olefins,CO2 emission reduction and acceleration of process commercialization via the combination of the process with other existing technologies.Compared with conventional steam cracking and methanol to olefins process,the direct production of lower olefins from syngas is economically competitive.
Keywords:syngas  Fischer-Tropsch  light olefins  technology progress  economic analysis
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