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Synthesis and Characterization of Y0.9-x GdxEu0.1 BO3 Phosphors by Spray Drying Process
作者姓名:王列松  林君  权泽卫
作者单位:KeyLaboratoryofRareEarthChemistryandPhysics.ChangchunInstituteofAppliedChemistry,ChineseAcademyofSciences,Changchun130022,China
基金项目:国家自然科学基金,科技部资助项目
摘    要:Y0.9-xGdxEu0. 1 BO3 phosphors were synthesized by spray drying (SD) method, and the results were compared with those by conventional solid state (SS) and citrate gel (CG) methods. The PL intensity of phosphors increases with the increase of x value in Y0.9-xGdxEu0.1BO3(prepared by SD) due to an energy migration process like Gd^3 - (Gd^3 )nEu^3 occurred in the material. Conlpared with the latter two methods, the phosphor particles prepared by spray drying method have a better morphology, such as homogeneous size (about 1 - 3μm) with spherical shape and smooth surface.Furthermore, the spray drying-derived phosphors have higher photoluminescence (PL) intensity than those by citrate gel method, but still a little lower than those by the solid state method.

关 键 词:Y0.9-xGdxEu0.1  荧光材料  合成  表征  喷雾烘干  稀土

Synthesis and Characterization of Y0.9-xGdxEu0.1BO3 Phosphors by Spray Drying Process
Wang Liesong,Lin Jun ,Quan Zewei.Synthesis and Characterization of Y0.9-x GdxEu0.1 BO3 Phosphors by Spray Drying Process[J].Journal of Rare Earths,2004,22(1):91-94.
Authors:Wang Liesong  Lin Jun  Quan Zewei
Affiliation:Wang Liesong,Lin Jun *,Quan Zewei
Abstract:Y0.9-xGdxEu0.1BO3 phosphors were synthesized by spray drying(SD) method, and the results were compared with those by conventional solid state(SS) and citrate gel(CG) methods. The PL intensity of phosphors increases with the increase of x value in Y0.9-xGdxEu0.1BO3(prepared by SD) due to an energy migration process like Gd3 -(Gd3 )n-Eu3 occurred in the material. Compared with the latter two methods, the phosphor particles prepared by spray drying method have a better morphology, such as homogeneous size(about 1~3 μm) with spherical shape and smooth surface. Furthermore, the spray drying-derived phosphors have higher photoluminescence(PL) intensity than those by citrate gel method, but still a little lower than those by the solid state method.
Keywords:optics  solid state chemistry  spherical phosphor  spray drying  rare earth borate
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