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Glass-forming Ability and Corrosion Resistance of Zr—Cu—Al—Co Bulk Metallic Glass
作者姓名:W.Zhou  W.P.Weng  J.X.Hou
作者单位:Shagang School of Iron and Steel, Soochow University
基金项目:financially supported by the National Natural Science Foundation of China (No. 51401139);the Basic Research Program of Jiangsu Province (No. BK20130304)
摘    要:Investigations were carried out to examine the effects of Co addition on the glass-forming ability(GFA)and corrosion resistance of Zr_(46)Cu_(46)(Al)_8 bulk metallic glass in chloride-containing solution. It is found that the GFA of(Zr_(46)Cu_(46)(Al)_8 )100-x Co x(x = 0, 1, 2, and 4 at.%) alloys reduces with the increase in Co content and correlates well with the parameters, such as the supercooled liquid region width ΔT x, the reduced glass transition temperature T rg and γ. The corrosion resistance is however found to be enhanced with the increase in Co concentration. The addition of Co causes the enrichment of Zr and Al, but depletes Cu in the surface films, which effectively enhances the corrosion potential and lowers the corrosion current densit

关 键 词:Bulk metallic glass  Co-addition  Glass-forming ability  Corrosion resistance
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