| 聚丙烯腈/水滑石插层共混体系的结构和性能研究 |
| |
| 引用本文： | 贾曌,田贵山,杨彦功.聚丙烯腈/水滑石插层共混体系的结构和性能研究[J].硅酸盐通报,2009,28(6):1332-1335. |
| |
| 作者姓名： | 贾曌 田贵山 杨彦功 |
| |
| 作者单位： | 山东理工大学材料科学与工程学院,淄博,255049 |
| |
| 摘 要： | 采用原位聚合法,以过氧化二苯甲酰为引发剂,在形成水滑石的同时单体丙烯腈进入其层间并发生聚合反应,制备出聚丙烯腈/水滑石插层复合材料.用红外光谱、扫描电镜和X射线衍射对这种插层复合材料的结构进行了分析和表征,并对其燃烧性能和热性能进行了初步研究.结果表明:在水滑石片层之间通过原位聚合的方法生成了聚丙烯腈大分子,使水滑石层间距有一定程度的增大.聚丙烯腈/水滑石共混复合物的阻燃性能有一定提高,其极限氧指数(LOI)从18%提高到了21%;耐热性能得到一定程度改善.
|
| 关 键 词： | 聚丙烯腈 水滑石 共混 原位聚合 |
Study on in Situ Polymerization of Polyacrylonitrile/layered Double Hydroxide(PAN/LDH) |
| |
| JIA Zhao,TIAN Gui-shan,YANG Yan-gong.Study on in Situ Polymerization of Polyacrylonitrile/layered Double Hydroxide(PAN/LDH)[J].Bulletin of the Chinese Ceramic Society,2009,28(6):1332-1335. |
| |
| Authors: | JIA Zhao TIAN Gui-shan YANG Yan-gong |
| |
| Affiliation: | JIA Zhao,TIAN Gui-shan,YANG Yan-gong(College of Material Science and Engineering,Shandong University of Technology,Zibo 255049,China) |
| |
| Abstract: | Using in situ polymerization,the monomer acrylonitrile(AN)was intercalated and polymerized with benzoyl peroxide(BPO)as the initiator between the layer of layered double hydroxide(LDH).The structure of Polyacrylonitrile/layered double hydroxide(PAN/LDH)was characterized by Fourier transformed infrared spectroscopy(FT-IR),scanning electron microscopy(SEM)and X-ray powder diffraction(XRD).Both the flame retardant property and heat resistant were investigated.The results showed that PAN has been prepared betwe... |
| |
| Keywords: | polyacrylonitrile layered double hydroxide blending in situ polymerization |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《硅酸盐通报》浏览原始摘要信息 |
|
点击此处可从《硅酸盐通报》下载全文 |
|
