On selection of standard states in adsorption isotherms |
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Authors: | B.E. Conway H. Angerstein-Kozlowska H.P. Dhar |
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Affiliation: | Chemistry Department, University of Ottawa, Ottawa Canada |
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Abstract: | The question of choice of appropriate standard states for adsorbed phases at electrode interfaces is reviewed and examined in relation to solvent displacement and the Langmuir and Flory-Huggins types of adsorption isotherms. Comparison with the situation for gas/solid adsorption is made. Standard potentials for electrochemisorption are considered for electrochemical isotherms with and without interaction/heterogeneity terms. |
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