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On selection of standard states in adsorption isotherms
Authors:B.E. Conway  H. Angerstein-Kozlowska  H.P. Dhar
Affiliation:Chemistry Department, University of Ottawa, Ottawa Canada
Abstract:The question of choice of appropriate standard states for adsorbed phases at electrode interfaces is reviewed and examined in relation to solvent displacement and the Langmuir and Flory-Huggins types of adsorption isotherms. Comparison with the situation for gas/solid adsorption is made. Standard potentials for electrochemisorption are considered for electrochemical isotherms with and without interaction/heterogeneity terms.
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