The revision on heat capacity of Einstein's solid model |
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作者姓名: | 王爱坤 周国香 李国昌 薛建华 |
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作者单位: | [1]SchoolofSciences,HebeiUniversityofTechnology,Tianjin300130,China. [2]SchoolofSciences,HebeiUniversityofTechnology,Tianjin300130,China//Dept.ofAppliedPhysics,HebeiUniversityofScienceandTechnology,Shijiazhuang050018,China [3]Dept.ofAppliedPhysics,HebeiUniversityofScienceandTechnology,Shijiazhuang050018,China |
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摘 要: | This paper is based on Einstein‘s supposition about crystal lattice vibration, which states that when Einstein‘s temperature ΘE is not less than the crystal temperature T but less than 2T, the expression of crystal molar heat capacity changes to the Dulong-Petit equation Cv= 3R. Thereby this equation can explain why crystal molar heat capacity equals about 3R not only at low temperatures but also at normal temperatures for many kinds of metals. It can be calculated that the nonlinear interaction among atoms contributes to the molar heat capacity using the coefficient of expansion β and the Griineisen constant γ. The result is that the relative error between the theoretical and the experimental value of the molar heat capacity is reduced greatly for many kinds of metals, especially for metals of IA. The relative error can be cut by about 17%.
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关 键 词: | 爱因斯坦固体模型 摩尔热容积 线性交互作用 扩展系数 |
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