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Surface Properties of Glucose-Based Surfactants and Their Application in Textile Dyeing with Natural Dyes
Authors:Li-Huei Lin  Hawn-Chung Chu  Keng-Ming Chen  Shih-Chieh Chen
Affiliation:1. Department of Cosmetic Science, Vanung University, 1, Van Nung Road, Taoyuan City, Taiwan, R.O.C.;2. Department of Applied Cosmetology, Lee-Ming Institute of Technology, 2-2 Lee-Juan Road, Lee-Ming Village, Taishan, Taipei, Taiwan, R.O.C.;3. Department of Polymer Engineering, National Taiwan University of Science and Technology, 43, Keelung Road, Section 4, Taipei, Taiwan, R.O.C.
Abstract:In this study, propylene glycol-based glycosides were obtained using an acetalization reaction in which glucose was first reacted with propylene glycol. Subsequently, the propylene glycol glycoside was reacted with alkyl glycidyl ether of varying carbon chain lengths (i.e., 08-G, 10-G, 12-G, 14-G, and 16-G) to synthesize a series of glucose-based biodegradable surfactants. The experimental results show that the surface activity of the C8–C12 glucose-based surfactants increases with the carbon chain length. However, the surface activity of the C14–C16 glucose-based surfactants decreased as the carbon chain length increased. Among all the surfactants, the C12 glucose-based surfactant exhibited the most efficient emulsification ability, lowest surface tension, lowest fluorescence intensity, highest zeta potential, and good emulsification stability. The glucose-based surfactants were used as additives in natural plant dyes made from turmeric or henna to dye wool fabrics. Higher color strengths were observed in the C14 glucose-based surfactant.
Keywords:Glucose  Surface activity  Emulsification  Natural plant dye
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