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不锈钢镀铬液有机添加剂新工艺
引用本文:朱有兰,陈海燕,舒畅. 不锈钢镀铬液有机添加剂新工艺[J]. 腐蚀与防护, 2006, 27(5): 247-250
作者姓名:朱有兰  陈海燕  舒畅
作者单位:广东工业大学材料与能源学院,广州,510640;广东工业大学材料与能源学院,广州,510640;广东工业大学材料与能源学院,广州,510640
摘    要:往常规镀铬溶液中加入有机添加剂,采用不同的电流密度、镀液温度、pH值和电镀时间进行镀铬,经过对镀层的形貌、厚度及结合力等性能进行比较取舍,获得了最佳镀液配方和工艺:CrO3250g/L,H2SO42.5g/L,Cr3 3g/L,甲醛8~10g/和丁二酸8~10g/L;在室温(20℃),镀液pH值为1.5,电流密度30A/dm2,电镀时间60min。该法既提高镀铬液的阴极电流效率又降低生产能耗,可获得光亮平滑、硬度高、结合力好的镀铬层。

关 键 词:不锈钢  镀铬  有机添加剂
文章编号:1005-748X(2006)05-0247-04
收稿时间:2005-07-25
修稿时间:2005-08-29

ORGANIC ADDITIVE AND PROCESS FOR CHROMIUM PLATING ON STAINLESS STEEL
ZHU You-lan,CHEN Hai-yan,SHU Chang. ORGANIC ADDITIVE AND PROCESS FOR CHROMIUM PLATING ON STAINLESS STEEL[J]. Corrosion & Protection, 2006, 27(5): 247-250
Authors:ZHU You-lan  CHEN Hai-yan  SHU Chang
Affiliation:Institute of Materials and Energy, Guangdong University of Technology, Guangzhou 510640, China
Abstract:By adding some additives in conventional chromium plating solution,some key parametess of the technological process for chromium plating,such as current density,working temperature and working time,were studied.The optimum formulation for the chromium plating was determined to be 250g/L CrO_3,2.5g/L H_2SO_4,3g/L Cr~(3 ),10g/L HCHO and 10g/L(CH_2COOH)_2,and the optimized parameters for the process were recommended as follows: room temperature,pH value of the solution 1.5,current density of 30A/dm~2 and electroplating time of 60 minutes.It could help not only to increase the cathodic current efficiency of the chromium-plating solution,but also to obtain smooth appearance,high hardness and wearability of chromium electrodeposits.
Keywords:Stainless steel  Chrome plate  Organic additive
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