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Hydrothermal reactions of dicalcium silicate and silica
Authors:George L Kalousek  Erik B Nelson
Affiliation:1. Colorado School of Mines Department of Chemistry and Geochemistry Golden, Colorado, USA;2. Dowell Division, Dow Chemical U.S.A.
Abstract:The kinetics of hydration of five C2SS cements at 0.83C/S were studied at 175 to 300°C. CSH(I) formed as the initial hydration phase in four cements and tobermorite in the other. Amounts of 1.32 and 1.74% CO2 in two cements caused total replacement of xonotlite by scawtite, while 0.34 and 0. 37 CO2 yielded negligible amounts of scawtite (if any). The equilibrium products in the two cements were scawtite and gyrolite at 175 and 200°C and scawtite and truscottite at 250 and 300°C.
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