| 2-甲氧基-3,5-二硝基-6-叠氮基吡嗪的合成 |
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| 引用本文： | 刘耀鹏,陈华雄,陈树森,金韶华. 2-甲氧基-3,5-二硝基-6-叠氮基吡嗪的合成[J]. 兵工学报, 2010, 31(10): 1357-1362 |
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| 作者姓名： | 刘耀鹏 陈华雄 陈树森 金韶华 |
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| 作者单位： | 陕西国防工业职业技术学院,陕西,西安,710302;北京理工大学,材料科学与工程学院,北京,100081 |
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| 摘 要： | 2-甲氧基-3,5-二硝基-6-叠氮基吡嗪(MDNAP)是一种新型含能化合物的母体,以2,6-二氯吡嗪为原料,经过甲氧基化合成得到2-甲氧基-6-氯吡嗪(MCP),得率81%.用硝硫混酸硝化MCP,在较温和的条件下得到2-甲氧基-3,5-二硝基-6-氯吡嗪(MDNCP),得率75%.MDNCP经叠氮化合成得到MDNAP,得率60%,各中间体均用IR、H1NMR、ESI-MS和EI-MS进行表征。
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| 关 键 词： | 有机化学 2-甲氧基-3 5-二硝基-6-叠氮基吡嗪 吡嗪 叠氮化 硝化 |
Synthesis of 2-methoxy-3,5-dinitryl-6-azidepyrazine |
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| LIU Yao-peng,CHEN Hua-xiong,CHEN Shu-sen,JIN Shao-hua. Synthesis of 2-methoxy-3,5-dinitryl-6-azidepyrazine[J]. Acta Armamentarii, 2010, 31(10): 1357-1362 |
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| Authors: | LIU Yao-peng CHEN Hua-xiong CHEN Shu-sen JIN Shao-hua |
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| Affiliation: | (1.Department of Chemical Engineering, Shaanxi Institute of Technology, Xi’an 710302， Shaanxi， China;2.College of Materials Science and Engineering , Beijing Institute of Technology , Beijing 100081, China) |
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| Abstract: | MDNAP is a precursor for novel energetic compounds.2-methoxy-6-chlorin pyrazine(MCP) was first synthesized from raw material 2,6-dichlorin pyrazine by substituting chlorine with methoxyl with a yield of 81%.2-methoxy-3,5-dinitryl-6-chlorin pyrazine(MDNCP) was obtained by the nitration of MCP with mixed nitric and sulfuric acids under facile conditions with a yield of 75%.2-methoxy-3,5-dinitryl-6-azide pyrazine(MDNAP) was synthesized from MDNCP by the zaide substitution of MDNCP with a yield of 60%.Therein,a... |
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| Keywords: | organic chemistry 2-methoxy-3 5-dinitryl-6-azidepyrazine pyrazine azide substitution nitration |
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