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Surface modification of synthetic fiber nonwoven fabrics with poly(acrylic acid) chains prepared by corona discharge induced grafting
Authors:Fusako Seto  Yoichiro Muraoka  Nobuyuki Sakamoto  Akio Kishida  Mitsuru Akashi
Abstract:The surface modification of synthetic fiber fabrics via corona discharge treatment and subsequent graft polymerization was investigated. Polyethylene (PE) nonwoven fabric and polyamide-6 (PA-6) nonwoven fabric were used as base fabrics. Acrylic acid (AAc) was graft polymerized onto the fabrics via corona discharge pre-treatment. The grafted amounts of PAAc were dependent on the grafting time, that of PA-6 being higher than that of PE. It was confirmed that the surface of the fibers constructing the fabric was fully covered with PAAc after the 20 min reaction. The surface of the PAAc grafted fabrics was characterized by X-ray photoelectron spectroscopy. The leakage of electrostatic charge from the fabric was determined and the dyeability was studied with methylene blue. The period of time in which the charge potential attenuated to 1/2 of the initial potential decreased drastically by grafting with PAAc. The grafted amount was enough for dyeing the entire fabrics.
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