| 磁性碳球的制备与表征 |
| |
| 引用本文： | 刘海星,杜泽峰,邱丽,李万捷,郭兴梅,刘旭光.磁性碳球的制备与表征[J].材料导报,2015,29(12):100-105. |
| |
| 作者姓名： | 刘海星 杜泽峰 邱丽 李万捷 郭兴梅 刘旭光 |
| |
| 作者单位： | 1. 太原理工大学化学化工学院,太原,030024;2. 太原理工大学化学化工学院，太原 030024; 太原理工大学教育部新材料界面科学与工程重点实验室，太原 030024 |
| |
| 摘 要： | 以葡萄糖、葡萄糖酸亚铁和十六烷基三甲基溴化铵(CTAB)为原料，采用水热法结合退火处理制得磁性碳球。重点考察了水热反应中反应物的浓度、反应温度和时间等参数对样品形貌和结构的影响。利用场发射扫描电子显微镜、X 射线衍射仪、X 射线光电子能谱、红外光谱仪、热重分析仪和振动磁强计等对所制备的磁性碳球进行表征。结果表明：当葡萄糖溶液浓度0.1 mol/L、葡萄糖酸亚铁质量浓度1.667 g/L、CTAB 质量浓度6.667 g/L、温度170℃、时间12 h 时，得到了粒径尺寸均一、表面光滑、形貌规整、分散性良好并且具有一定铁磁性的碳球，其平均粒径约为600 nm。此外，分析了磁性碳球的形成机理。
|
| 关 键 词： | 水热法 磁性碳球 制备条件 官能团 |
Preparation and Characterization of Magnetic Carbon Spheres |
| |
| LIU Haixing,DU Zefeng,QIU Li,LI Wanjie,GUO Xingmei and LIU Xuguang.Preparation and Characterization of Magnetic Carbon Spheres[J].Materials Review,2015,29(12):100-105. |
| |
| Authors: | LIU Haixing DU Zefeng QIU Li LI Wanjie GUO Xingmei and LIU Xuguang |
| |
| Affiliation: | College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024 and College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024;Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education,Taiyuan University of Technology, Taiyuan 030024 |
| |
| Abstract: | Magnetic carbon spheres (MCSs )were prepared by a combined methodology of hydrothermal method and annealing treatment using glucose,ferrous gluconate and hexadecyltrimethylammonium bromide (CTAB) as raw materials.The effects of reactant precursor concentration,reaction temperature and reaction time on the mor-phology and structure of MCSs were investigated.The samples were characterized by field emission scanning electron microscopy,X-ray diffraction,X-ray photoelectron spectroscopy,Fourier transform infrared spectroscopy,thermo-gravimetry and vibrating sample magnetometer.Results showed that MCSs,with regular morphology,smooth sur-face,good dispersibility,and ferromagnetism were obtained when glucose concentration was 0.1 mol/L,ferrous glu-conate concentration was 1.667 g/L,CTAB concentration was 6.667 g/L at 1 70 ℃ for 12 h.The average diameter of MCSs was about 600 nm.Meanwhile,a possible formation mechanism of MCSs was proposed. |
| |
| Keywords: | hydrothermal method magnetic carbon spheres preparation condition functional groups |
| 本文献已被 万方数据 等数据库收录！ |
| 点击此处可从《材料导报》浏览原始摘要信息 |
|
点击此处可从《材料导报》下载全文 |
|
