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Nitrogen chemistry in coal pyrolysis: Catalytic roles of metal cations in secondary reactions of volatile nitrogen and char nitrogen
Authors:Naoto Tsubouchi  Yasuo Ohtsuka
Affiliation:Research Center for Sustainable Materials Engineering, Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira, Aoba-ku, Sendai 980-8577, Japan
Abstract:The present review focuses on elucidating the chemistry of nitrogen release during coal pyrolysis, in particular, on making clear catalytic roles of inherent Ca and Fe ions in not only the partitioning of volatile-N to tar-N, HCN, NH3 and N2 but also the conversion of char-N to N2.
Keywords:Coal pyrolysis  Nitrogen release  Volatile nitrogen  Char nitrogen  Secondary reactions  Metal cations  N2 formation
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