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D2EHPA萃取分离锌和镍试验研究
引用本文:王瑞永,黄中省. D2EHPA萃取分离锌和镍试验研究[J]. 有色冶金设计与研究, 2013, 0(6): 18-22
作者姓名:王瑞永  黄中省
作者单位:紫金矿业集团股份有限公司低品位难处理黄金资源综合利用国家重点试验室,福建上杭364200
基金项目:国家重点基础研究发展计划项H(NO.2010CB735502);国家重点基础研究发展计划项H(NO.2012CB724202);福建省杰出青年基金项目f2011J0103).
摘    要:采用D2EHPA溶剂对含锌镍酸性溶液进行萃取分离锌、镍试验研究,在最佳萃取、反萃分离条件下,锌的萃取、反萃率分别为99.34%、99.79%,镍的萃取、反萃率分别为99.16%、99.58%,锌镍分离系数达25000以上,得到的含锌、含镍反萃液分别符合电解锌、电解镍的技术要求。

关 键 词:溶剂萃取法  锌镍  D2EHPA  反萃

Research on the Solevent Extraction Separate of Zinc and Nickle Using D2EHPA
WANG Rui-yong,HUANG Zhong-sheng. Research on the Solevent Extraction Separate of Zinc and Nickle Using D2EHPA[J]. , 2013, 0(6): 18-22
Authors:WANG Rui-yong  HUANG Zhong-sheng
Affiliation:(Zijin Mining Group Co.Ltd State Key Laboratory of Comprehensive Utilization of Low-Grade Refractory Gold Ores, Shanghang, Fujian, 364200,China)
Abstract:The paper studied that the sulphuric acid solution contained zinc and nickel were separated by solvent extraction using D2EHPA as extraction agent.The results showed that ,in the best conditions,the extraction and back-extraction ratio of zinc reached 99.34% and 99.79%, respectively. The extraction and back-extraction ratio of nickel reached 99.16% and 99.58%, respectively.The separation factor of zinc and nickel was more than 25 000.The content of Zn and Ni in the back-extraction solution respectively conform the electrolysis requirements.
Keywords:solvent extraction  zinc and nickel  D2EHPA  back extraction
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