| 负载贵金属的层柱分子筛抗硫中毒性能研究 |
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| 引用本文： | 刘维桥,阎富山,孙桂大,达志坚,闵恩泽.负载贵金属的层柱分子筛抗硫中毒性能研究[J].辽宁石油化工大学学报,1996(4). |
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| 作者姓名： | 刘维桥 阎富山 孙桂大 达志坚 闵恩泽 |
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| 作者单位： | 材料科学与技术研究所，石油化工科学研究院 |
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| 摘 要： | 以苯为模型化合物研究了负载贵金属的层柱分子筛（ＰＬＣ）催化剂在苯加氢反应中的抗硫性能。考察了在Ａｌ－ＣＬＭ和Ａｌ－ＣＬＢ上负载Ｐｔ或Ｐｄ的单金属催化剂和负载双金属Ｐｔ和Ｐｄ催化剂的抗硫性能，不同的Ｐｔ／Ｐｄ比对催化剂抗硫性能的影响。结果表明，Ｐｔ（Ｐｄ）／ＰＬＣ的抗硫性能远远低于Ｐｔ（Ｐｄ）／γ－Ａｌ２Ｏ３催化剂的抗硫性能；Ｐｔ／ＰＬＣ抗硫性能优于Ｐｄ／ＰＬＣ的抗硫性能；Ｐｔ（Ｐｄ）／Ａｌ－ＣＬＭ的抗硫性能优于Ｐｔ（Ｐｄ）／Ａｌ－ＣＬＢ催化剂的抗硫性能；Ｐｔ－Ｐｄ／ＰＬＣ的抗硫性能较单金属催化剂的抗硫性能得到明显改善，且Ｐｔ／Ｐｄ比对其抗硫性能有重要影响，当含Ｐｔ的质量分数为０．３％，含Ｐｄ的质量分数为０．９％时，Ｐｔ－Ｐｄ／Ａｌ－ＣＬＭ催化剂的抗硫性能最佳。
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| 关 键 词： | 层柱分子筛 抗硫性能 贵金属催化剂 苯加氢 |
Study on the Ability to Resistance to Sulphur-Poisoning over Pillared-Layer Clay Loaded with Precious Metals |
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| Liu Weiqiao,Yan Fushan,Sun Guida.Study on the Ability to Resistance to Sulphur-Poisoning over Pillared-Layer Clay Loaded with Precious Metals[J].Journal of Liaoning University of Petroleum & Chemical Technology,1996(4). |
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| Authors: | Liu Weiqiao Yan Fushan Sun Guida |
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| Abstract: | The behavior of the sulphur-resistance of the hydrogenation of benzene as model chemical compound over pillared-layer clays(PLC) loaded with precious metals was studied. The results showed that the behavior of the sulphur-resistance of the Pt (Pd)/γ-Al 2O 3 was superior to that of Pt(Pd)/PLC, The behavior of the sulphur-resistance of the Pt/PLC was superior to that of Pd/PLC, The behavior of the sulphur-resistance of the Pt(Pd)/Al-CLM was superior to that of Pt(Pd)Al-CLB,The behavior of the sulphur-resistance of the Pt-Pd/PLC compared to the single metal catalysts is clearly improved. The ration of Pt/Pd has very important effect on the behavior of the sulphur-resistance of the Pt-Pd/PLC and the behavior of the sulphur-resistance of the Pt-Pd/PLC is the best when the catalyst contain Pt 0.3%,Pd 0.9% |
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| Keywords: | PLC Behavior of the sulphur-resistance Precious metal catalysts Hydrogenation of benzene |
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