| 3-(3’-戊基醚)-1,4-环己二烯-1-羧酸乙酯的合成 |
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| 引用本文： | 孔黎春,陈东旭,朱钢国.3-(3’-戊基醚)-1,4-环己二烯-1-羧酸乙酯的合成[J].浙江化工,2012(9):11-14. |
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| 作者姓名： | 孔黎春 陈东旭 朱钢国 |
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| 作者单位： | 浙江师范大学化学与生命科学学院 |
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| 基金项目： | 浙江省钱江人才计划项目(2010R10016);浙江省分析测试项目(2011C37051) |
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| 摘 要： | 采用3-硝基丙烯酸乙酯和1,3-丁二烯基-3-戊基醚为原料,通过一个Diels-Alder反应和硝基消除反应以两步54%的总产率顺利地合成了3-(3’-戊基醚)-1,4-环己二烯-1-羧酸乙酯化合物。
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| 关 键 词： | 3-(3’-戊基醚)-1 4-环己二烯-1-羧酸乙酯 Diels-Alder反应 3-硝基丙烯酸乙酯 1 3-丁二烯基-3-戊基醚 |
Synthesis of Ethyl 3-(Pentan-3-yloxy)cyclohexa-1,4-dienecarboxylate |
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| KONG Li-chun,CHEN Dong-xu,ZHU Gang-guo.Synthesis of Ethyl 3-(Pentan-3-yloxy)cyclohexa-1,4-dienecarboxylate[J].Zhejiang Chemical Industry,2012(9):11-14. |
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| Authors: | KONG Li-chun CHEN Dong-xu ZHU Gang-guo |
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| Affiliation: | (College of Chemistry and Life Science,Zhejiang Normal University,Jinhua Zhejiang 312004,China) |
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| Abstract: | Ethyl 3-(pentan-3-yloxy)cyclohexa-1,4-dienecarboxylate was synthesized in 54% yield over 2 steps via the Didls-Alder reaction of 3-(buta-1,3-dien-1-yloxy)pentane and ethyl 3-nitroacrylate followed by elimination of nitro group. |
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| Keywords: | ethyl 3-(pentan-3-yloxy)cyclohexa-1 4-dienecarboxylate ethyl 3-mitroacrylate Diels-Alder reaction 3-(buta-1 3-dien-1-yloxy)pentane |
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