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超声波对硫酸盐镀镍及镀层性能的影响研究
引用本文:李延伟,尚雄,黄晓曦,吕频,杨哲龙.超声波对硫酸盐镀镍及镀层性能的影响研究[J].电镀与精饰,2012,34(6):10-13,32.
作者姓名:李延伟  尚雄  黄晓曦  吕频  杨哲龙
作者单位:1. 桂林理工大学化学与生物工程学院,广西桂林,541004
2. 桂林长海发展有限责任公司,广西桂林,541001
3. 哈尔滨工业大学化工学院,黑龙江哈尔滨,150001
基金项目:广西自然科学基金(桂科自0991247);广西教育厅项目(200802LX191)
摘    要:研究了硫酸盐镀镍过程中施加超声波对阴极极化能力、阴极电流效率、分散能力、电化学反应阻抗、镀层内应力和硬度的影响。结果表明,镀镍过程中施加超声波能够降低阴极极化、提高阴极电流效率、改善电解液的分散能力、减小镍沉积阻抗;还能细化镀层晶粒、降低镀层内应力、提高镀层的硬度。

关 键 词:镀镍  硫酸盐  超声波  电流效率  内应力

Effects of Ultrasonic on the Process and Characteristics of Nickel Electrodeposition in Sulfate Electrolyte
LI Yan-wei , SHANG Xiong , HUANG Xiao-xi , LV Pin , YANG Zhe-long.Effects of Ultrasonic on the Process and Characteristics of Nickel Electrodeposition in Sulfate Electrolyte[J].Plating & Finishing,2012,34(6):10-13,32.
Authors:LI Yan-wei  SHANG Xiong  HUANG Xiao-xi  LV Pin  YANG Zhe-long
Affiliation:1.College of Chemistry and Bioengineering,Guilin University of Technology,Guilin 541004,China;2.Guilin Changhai Development Company,Guilin 541001,China;3.School of Chemical Engineering and Technology,Harbin Institute of Technology,Harbin 150001,China)
Abstract:The effects of ultrasonic on the cathodic polarization ability,cathodic current efficiency,throwing power,electrochemical reaction impedance,internal stress and hardness of nickel deposition in sulfate electrolyte were investigated.Results showed that the introduction of ultrasonic during nickel electroplating could reduce the cathodic polarization,increase the cathodic current efficiency,improve the throwing power and decrease the electrochemical reaction impedance of the nickel deposition.Moreover,the introduction of ultrasonic could also refine the grain size,decrease the internal stress and increase the hardness of nickel coating.
Keywords:nickel electro-deposition  sulfate  ultrasonic  current efficiency  internal stress
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