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The Electrical Conductivity of Strontium-Barium Niobate
Authors:G. D. Mahan  J. O. Sofo
Affiliation:1. Department of Physics, Pennsylvania State University, University Park, PA, 16802, USA
2. Department of Materials Science and Engineering, Pennsylvania State University, University Park, PA, 16802, USA
Abstract:We propose an explanation for the high electrical conductivity of the ferroelectric strontium-barium niobate. As the temperature T approaches the ferroelectric transition T c, the static dielectric constant $varepsilon(0)$ diverges when a soft mode occurs. This divergence of $varepsilon(0)$ reduces the donor binding energy, and increases the effective Bohr radius of the donor. The electrons bound to the donors become unbound, and the material becomes conductive.
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