An amorphous silicon random nanocone/polymer hybrid solar cell |
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Authors: | Zingway Pei Subramani ThiyaguMing-Sian Jhong Wei-Shang HsiehShor-Jen Cheng Min-Wei HoYu-Hung Chen Jun-Chin LiuChun-Ming Yeh |
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Affiliation: | a Graduate Institute of Optoelectronic Engineering, Department of Electrical Engineering, National Chung Hsing University, Taichung 40227, Taiwan, ROC b Photovoltaic Technology Division, Green Energy and Environment Research Laboratories (GEL), Industrial Technology Research Institute (ITRI), Hsinchu 31040, Taiwan, ROC. |
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Abstract: | This paper proposes and experimentally demonstrates an a-Si:H random nanocone/PEDOT:PSS/P3HT:PCBM hybrid solar cell to extend the absorption to near infrared and solve the difficulty of carrier transport through organic-inorganic interface. The internal electrical field inside a-Si:H random nanocone force holes move to the anode and electrons move to the cathode. The insertion of a layer of PEDOT:PSS conducting polymer between organic-inorganic interface could cause electrons and holes to partially recombine, thus establishing an electrically connected a-Si:H and P3HT:PCBM bulk heterojunction, which enables carriers transport through organic-inorganic interfaces efficiently. As compared to conventional polymer solar cells, the open-circuit voltage of hybrid solar cells was increased from 0.51 to 0.78 V. Additionally, the power conversion efficiency was increased from 1.73% to 2.22%, which demonstrates approximately 28% enhancement, indicating that the hybrid structure could largely increase the efficiency of polymer solar cells. |
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Keywords: | Random nanocones Amorphous silicon Hybrid solar cell |
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