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Effect of debris on the silicon wafering for solar cells
Authors:A Bidiville  I Neulist  K WasmerC Ballif
Affiliation:a Q-Cells SE, OT Thalheim, Sonnenallee 17-21, DE-06766 Bitterfeld-Wolfen, Germany
b Ecole Polytechnique Fédérale de Lausanne (EPFL), Institute of Microengineering (IMT), Photovoltaics and Thin Film Electronics Laboratory, Rue A.-L. Breguet 2, CH-2000 Neuchâtel, Switzerland
c Empa—Swiss federal laboratories for material testing and research, Laboratory for Materials Technology, Feuerwerkstrasse 39, CH-3602 Thun, Switzerland
Abstract:The wafers used by the photovoltaic industry are mostly produced by multi-wire slurry sawing. One of the key factors determining the wafer quality (presence of saw marks and chips, increased roughness, wafer thickness variations and wafer strength) is the abrasive slurry. For cost reduction, the slurry is regularly exchanged and the debris it contains is removed in a recycling operation. To optimise the slurry usage, it is of utmost importance to understand the effects of the silicon debris concentration in the slurry. This was studied by sawing several bricks one after the other with the same slurry. It was found that when the amount of debris is too high (more than 4% of the slurry volume), saw marks appear on the wafers and they become more fragile. Finally, a first qualitative model explaining the apparition of the saw marks and the reduction of wafer strength is proposed.
Keywords:Silicon  Wafer  Wire-sawing  Debris  Breakage strength
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