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HNO3-H2C2O4体系中Np和Pu的分离研究
引用本文:梁俊福,汪南杰. HNO3-H2C2O4体系中Np和Pu的分离研究[J]. 核科学与工程, 2001, 21(1): 64-70
作者姓名:梁俊福  汪南杰
作者单位:清华大学核能技术设计研究院,
基金项目:国家“九五”科技攻关项目96A18-02-02
摘    要:研究了30%TBP-煤油在不同的硝酸-草酸混合溶液中对Np,Pu各价态的萃取分配,在HNO

关 键 词:HNO
修稿时间:2000-03-14

Solvent Extraction and Separation of Np and Pu in Mixed H2C2O4-HNO3 System
LIANG Junfu. Solvent Extraction and Separation of Np and Pu in Mixed H2C2O4-HNO3 System[J]. Chinese Journal of Nuclear Science and Engineering, 2001, 21(1): 64-70
Authors:LIANG Junfu
Abstract:The separation of Np,Pu has been studied in mixed H 2C 2O 4 HNO 3 30% TBP kerosene. In condition of high acidity,the dissociation of H 2C 2O 4 is inhibited,and the influence of H 2C 2O 4 upon Np,Pu extraction ability by 30% TBP kerosene as extractant has been eliminated in certain degree. According to the difference of HNO 3 and H 2C 2O 4 acidity, Np,Pu extraction contribution ratios of 30% TBP kerosene are given, on the basis of it,one technological process of separation of Np,Pu with extraction of 30% TBP kerosene and each technological parameter are recommended.
Keywords:HNO 3 H 2C 2O 4 system  neptunium  plutonium  separation
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