Preparation and characterization of a number of amine salts of long-chain fatty acids |
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Authors: | Robert R Mod Frank C Magne Evald L Skau |
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Affiliation: | (1) Southern Regional Research Laboratory, New Orleans, Louisiana |
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Abstract: | Summary Eighty-eight amine salts of long-chain fatty acids have been prepared, purified by solvent crystallization, and characterized.
Forty-five of these were salts of palmitic acid. The rest included salts of capric, lauric, myristic, stearic, oleic, elaidic,
and 12-hydroxystearic acids. A variety of aliphatic, aromatic, and heterocyclic amines, including primary, secondary, and
tertiary amines, were investigated. The majority of these gave 1∶1 acid-amine compounds on solvent recrystallization of an
equimolar mixture of acid and amine. Some of the amines gave no crystallizable salt, and with others the pure salt could not
be obtained by this procedure. Under the same conditions the symmetrical alkyl, substituted alkyl, and aralkyl secondary amines
investigated gave crystallizable compounds containg two molecules of fatty acid to one of amine. Molecular compounds of 2-aminopyridine
with four molecules of saturated fatty acid were formed by recrystallization starting with a 1 to 4 amine-acid mixture. Surface-tension
measurements were made for aqueous solutions of a few of the amine salts.
One of the laboratories of the Southern Utilization Research and Development Division, Agricultural Research Service, U. S.
Department of Agriculture. |
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